Cryochemical kinetic parameters of a Menshutkin reaction

Authors: Kizilova A.S.
Published in issue: #2(7)/2017
DOI: 10.18698/2541-8009-2017-2-68
Category: Power, Metallurgic and Chemical Engineering | Chapter: Machines and Devices, Processes of Refrigeration and Cryogenic Engineering, Air Conditioning
Keywords: kinetics, analysis, reaction, refrigerated solution, process rate
Published: 30.03.2017

The article deals with the specifics of cryochemical processes. We present cryochemical kinetic parameters of a Menshutkin reaction based on a chemical process model and on the kinetics and reaction mechanisms studied for various types of reactions in refrigerated solutions.

References

[1] Stepanov M.B., Volkov A.A. On question of chemical reaction behavior in solvents. Problem setting. Science Time, 2016, no. 5, pp. 634-638 (in Russ.).

[2] Kizilova A.S. Reaction kinetics analysis of diacetone decompounding in frozen solutions. Molodezhnyy nauchno-tekhnicheskiy vestnik [Electronic Periodical Youth Scientific and Technical Bulletin], no. 9. URL: http://sntbul.bmstu.ru/doc/849499.html (accessed 01.12.2016) (in Russ.).

[3] Vatsuro K.V., Mishchenko G.P. Imennye reaktsii v organicheskoy khimii [Nominal reactions in organic chemistry]. Moscow, Khimiya Publ., 1976. 528 p. (in Russ.).

[4] Stepanov M.B. Kinetika i mekhanizm nekotorykh khimicheskikh reaktsiy v zamorozhennykh rastvorakh. Dis. kand. khim. nauk [Kinetics and mechanism of some chemical reactions in frozen solutions. Kand. tech. sci. diss.]. Moscow, Lomonosov MSU Publ., 1973. 133 p. (in Russ.).

[5] Korovin N.V., Maslennikova G.N., Mingulina E.I., Filippov E.L. Kurs obshchey khimii [General chemistry course]. Moscow, Vysshaya shkola Publ., 1990. 446 p. (in Russ.).