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Chemical heat treatment of steels with super-equilibrium nitrogen concentration

Authors: Goncharevskaya D.A.
Published in issue: #8(49)/2020
DOI: 10.18698/2541-8009-2020-8-636


Category: Metallurgy and Science of Materials | Chapter: Metal Science, Thermal Processing of Metals and Alloys

Keywords: steels of the martensitic class, super-equilibrium concentration of nitrogen, chemical heat treatment, vacuum nitriding, vacuum carburizing, diffusion layer thickness, carbides, nitrides
Published: 07.09.2020

The paper presents the results of studies of 5KhNM type martensitic steel, in which part of the carbon is replaced by nitrogen with various super-equilibrium concentrations. The regularities of the diffusion saturation of the surface layers of steels with carbon are established depending on the saturation time and the initial nitrogen content. Data on the structure and properties of steels in the initial state and after chemical-thermal and heat treatment are presented. The analysis is carried out of the saturation kinetics of steels during vacuum carburizing and vacuum nitriding. It is shown that the use of chemical-thermal treatment makes it possible to more fully realize the potential of steels containing a super-equilibrium nitrogen concentration.


References

[1] Shchukina L.E. Issledovanie i razrabotka protsessa legirovaniya metalla azotom v agregatakh spetsial’noy elektrometallurgii s tsel’yu povysheniya kachestva stali. Avtoref. diss. kand. tekh. nauk [Study and development of metal alloying process by nitrogen atoms in special electrometallurgy devices with the purpose of raising quality of steel. Abs. kand. tech. sci. diss.]. Moscow, MISiS Publ., 2018 (in Russ.).

[2] Uggowitzer P.J., Harzenmoser M. Strengthening of austenite stainless steels by nitrogen. Proc. HNS 88. London, Institute of Metals, 1989, pp. 174–179.

[3] Gavriljuk V.G., Duz’ V.A., Yephimenko S.P. Gehalte an C, P, S und N im Stahl. Proc. HNS 90. Stein G., Düsseldorf, Witulski H. Stahl und Eisen, 1990, pp. 100–103.

[4] Azuma S., Miyuki H., Kudo T. Effect of alloying nitrogen on crevice corrosion of austenitic stainless steels. ISIJ Int., 1996, vol. 7, no. 36, pp. 793–798. DOI: https://doi.org/10.2355/isijinternational.36.793

[5] Gavrilyuk V.G. Influence of interstitial carbon, nitrogen, and hydrogen on the plasticity and brittleness of steel. Chernaya metallurgiya, 2015, vol. 58, no. 10, 2015, pp. 761–768. DOI: https://doi.org/10.17073/0368-0797-2015-10-761-768 (in Russ.). (Eng. version: Steel Transl., 2015, vol. 45, no. 10, pp. 747–753. DOI: https://doi.org/10.3103/S0967091215100046)

[6] Shabalov I.P., Shlyamnev A.P., Shchukina L.E. Structure, mechanical properties and corrosion resistance of stainless steels alloyed with nitrogen. Problemy chernoy metallurgii i metallovedeniya, 2016, no. 1, pp. 1–7 (in Russ.).

[7] Rashev Ts. Vysokoazotistye stali. Metallurgiya pod davleniem [High-carbon steels. Metallurgy under pressure]. Sofiya, Prof. Marin Drinov Publ., 1995 (in Russ.).

[8] Svyazhin A.G. Nitrogen-alloyed steels. Izvestiya vuzov. Chernaya metallurgiya [Izvestiya. Ferrous Metallurgy], 2005, no. 10, pp. 36–46 (in Russ.).

[9] Lakhtin Yu.M., Arzamasov B.N. Khimiko-termicheskaya obrabotka metallov [Thermochemical treatment of metals]. Moscow, Metallurgiya Publ., 1985 (in Russ.).

[10] Arzamasov B.N., ed. Materialovedenie [Material science]. Moscow, Bauman MSTU Publ., 2008 (in Russ.).

[11] Bannykh I.O., Bannykh O.A., Antsyferova M.V., et al. Substantiation of composition choice and the melting of medium-carbon low-alloyed strain-hardened nitrogen-containing steel under conditions of electroslag remelting at increased nitrogen pressure. Elektrometallurgiya, 2018, no. 5, pp. 24–29 (in Russ.).

[12] Bigeev A.M., Bigeev V.A. Metallurgiya stali [Steel metallurgy]. Magnitogorsk, Nosov MSTU Publ., 2000 (in Russ.).

[13] Gulyaev A.P. Metallovedenie [Material science]. Moscow, Metallurgiya Publ., 1986 (in Russ.).